The absorption and desorption behaviors of NH3 in solid CaCl2-CaBr2 were investigated using the pressure-swing method at 473 K. Various compositions of CaCl2-CaBr2 solid mixture particles were formed by the impregnation method, and the solid-mixture effect on the NH3 absorption behavior was evaluated. The compositional changes in the lattice sizes followed Vegard's law. For the solid mixture, the absorption rate of NH3 increased because NH3 was absorbed into CaCl2-CaBr2 at a lower energy and higher rate than CaCl2 single salt. For x = 1.67 in CaCl x Br2-x , the highest storage capacity was obtained; however, NH3 desorption was not observed until x ≤ 1.00 in CaCl x Br2-x , similar to the findings of CaBr2 single salt. Two absorption energy curves were observed for CaCl2-CaBr2 with different compositions, indicating the formation of solid mixtures with different solvent lattices, namely, a CaCl2-CaBr2 solid mixture in the CaCl2 and CaBr2 lattices, respectively. After five cycles of NH3 absorption/desorption, degradations such as capacity fade and phase segregation in the CaCl2-CaBr2 particles were not observed, confirming their stability toward these processes at 473 K.