Rising demand for products incorporating e-textiles is catalyzing development of innovative coating and processing techniques to produce robust conductive fabrics that can tolerate demanding wear/wash cycles without losing function.Tremendous variation in the elec. performance and ruggedness of e-textiles can be observed with different conductive coatings and processing conditions.Intrinsically-conducting polymers (ICPs)-primarily carbon-based organic polymers that conduct electricity like metals-are lightweight, are not oxidized or corroded upon exposure to sweat/moisture and salt, have the same mech. characteristics as known textiles, and can be applied as coatings using multiple techniques.In particular, chem. vapor deposition (CVD), a reactive coating method that uses mol. precursors to produce films via an in situ chem. reaction allows for ICP films to directly form on the surface of any pre-made garment, pre-woven fabric or fiber/yarn substrate, without added binders, surface pretreatments, detergents or fixing agents.CVD produces uniform, conformal, high-conductivity ICP coatings on yarn and fabric surfaces.ICP coatings produced via CVD are exceptionally laundering- and wear-stable, are resilient against mech. washing, and can be non-disruptively applied at the end of existing, high-throughput textile and garment manufacturing routines.Due to the speed of the foundational organic chem. reaction (polymerization) that drives the coating process, film growth rates of ICPs with CVD are orders of magnitude faster than traditional CVD processes used for metal and metal oxide counterparts, meaning that the specific material and process combination of ICPs and CVD is uniquely positioned for successful scale-up to the industrial, high-throughput level.