Yokohama National University

Carbon fiber-reinforced ultra-high-temperature ceramic (UHTC) matrix composites are extensively used in space shuttles and high-speed vehicles. However, these composites suffer from a lack of oxidation resistance. Recently, researchers tested the heat resistance of these composites at very high temperatures, providing insight into the modifications needed to prevent UHTC degradation. Their findings could have huge implications for the manufacture of space shuttle orbiters. Carbon fiber-reinforced carbon (C/C) is a composite material made of carbon fiber reinforced in a matrix of glassy carbon or graphite. It is best known as the material used in hypersonic vehicles and space shuttle orbiters, which cruise at speeds greater than Mach 5. Since the 1970s, it has also been used in the brake system in Formula One racing cars. Even though C/C has excellent mechanical properties at high temperatures and inert atmospheres, it lacks oxidation resistance in these conditions, making its widespread use limited. Researchers have found that ultra-high-temperature ceramics (UHTCs), which include transition metal carbides and diborides, show good oxidation resistance. In previous studies, zirconium-titanium (Zr-Ti) alloy infiltration has shown promising results for improving the heat resistance of carbon fiber-reinforced UHTC matrix composites (C/UHTCMCs). However, their use at high temperatures (>2000 oC) is not known. Set against this backdrop, a group of researchers from Japan have evaluated the potential utility of Zr-Ti alloy-infiltrated C/UHTCMCs at temperatures above 2000 oC. Their study, led by Junior Associate Professor Ryo Inoue from Tokyo University of Science (TUS), was published in the Journal of Materials Science and made available online on October 27, 2022. The research team consisted of Mr. Noriatsu Koide and Assistant Professor Yutaro Arai from TUS, Professor Makoto Hasegawa from Yokohama National University, and Dr. Toshiyuki Nishimura from the National Institute for Materials Science. Speaking of the motivation behind their study, "The research is an extension of the research and development of ceramics and ceramics-based composite materials. In recent years, we have received inquiries from several manufacturers of heavy industries regarding materials that can be used at temperatures above 2000 °C. We have also started to work with these manufacturers to develop new materials," says Prof. Inoue. The C/UHTCMC was manufactured using melt infiltration, which is the most cost-effective way to fabricate these materials. To study the applicability of this material, three types of C/UHTCMCs were fabricated with three different alloy compositions. The three alloy compositions used had varying atomic ratios of Zr:Ti. To characterize the heat resistance, the team used a method called arc-wind tunnel testing. This method involves exposing the material to extremely high enthalpy airflow inside a tunnel, similar to conditions that spacecrafts experience while re-entering the atmosphere. The team found that the amount of Zr in the alloy had a strong effect on the degradation of the composite for all temperatures. This is owing to the thermodynamic preference for the oxidation of Zr-rich carbides compared to Ti-rich carbides. Further, the Zr and Ti oxides formed on the composite surface prevented further oxidation, and the oxide composition depended on the composition of the infiltrated alloys. Thermodynamic analysis revealed that the oxides formed on the composite surface were composed of ZrO2, ZrTiO4, and TiO2 solid solutions. At temperatures above 2000 oC, the thickness and weight of the samples increased with the Zr content of the composites after the arc-wind tunnel tests. The team also observed that the melting point of the surface oxides increased as the Zr content increased. For temperatures above 2600 oC, the only oxides formed were liquid-phase, requiring a thermodynamic design of the matrix composition to prevent the recession of UHTC composites. "We have successfully studied the degradation of C/UHTCMC at temperatures above 2000 oC using thermodynamic analysis. We have also shown that the matrix design needs modification to prevent the degradation of the composites. Our research has the potential to contribute to the realization of ultra-high-speed passenger aircraft, re-entry vehicle, and other hypersonic vehicles,"concludes Prof. Inoue. These results could have important consequences in the production of advanced space shuttle orbiters and high-speed vehicles.

Approximately 60% of babies have jaundice, according to the CDC. Jaundice occurs when a newborn’s liver is not sufficiently developed to take over the chore of removing bilirubin from the baby’s blood, which was done by the mother’s liver prior to birth. Untreated jaundice can result in brain damage and a scary menu of additional serious health problems. Hospitals monitor newborns closely for jaundice after birth; a visit to the pediatrician a day or two after discharge includes a bilirubin check. Jaundice is often easy to observe from its characteristic yellowing skin, but it’s not always noticeable, especially with newborn babies of color. A better check of a baby’s bilirubin level requires a light meter placed on the forehead. A blood test is the most accurate way to measure bilirubin. Direct light exposure (phototherapy) on the skin is the most common treatment method for jaundice, although doctors might treat severe cases of very high bilirubin levels with a blood exchange transfusion. We first wrote about newborn jaundice treatment technology in 2015 when we covered NeoMedLight’s light blanket with fiber optic material woven into textiles. We also wrote about TheraB Medical’s SnugLit, a wearable phototherapy garment. Wearables now hope to address the problem of diagnosing jaundice. Researchers from Yokohama National University’s Graduate School of System Integration and Yokohama City University’s Graduate School of Medicine Department of Pediatrics developed a wearable device for babies that continuously monitors pulse rate, blood oxygen saturation, and bilirubin level. The team published their results in Science Advances. The new device uses LEDs to transmit light to the skin on the newborn’s forehead. According to the study report and a news release from Japan Agency for Medical Research and Development, the wearable consistently measured bilirubin independently, even during phototherapy. The team tested the device with 50 babies. The results were insufficiently accurate for clinical decision support, a failure the researchers believe is due to the device’s overall thickness. The group’s next steps include increasing the device flexibility and using thin film batteries instead of the coin cell battery used with the first device. The researchers also plan to develop a combined phototherapy device that also monitors bilirubin level.